Advanced high strength steels, such as dual-phase and martensitic steels, are increasingly being used by automakers to decrease the thickness of steel sheet used in parts without sacrificing part strength. When welded, the martensite within the dual-phase and martensitic steel microstructures tempers, reducing the heat-affected zone (HAZ) hardness compared to the base material, locally reducing strength. This process is known as HAZ softening. HAZ softening has been well studied; however, the kinetics of this process has not been quantified and the processes responsible for HAZ softening have not been examined. This thesis investigated both of these topics.
HAZ softening was modelled using the Johnson-Mehl-Avrami-Kolmogorov (JMAK) equation. As the thermal profile during welding is non-isothermal, the effects of temperature and time on steel tempering kinetics could not be separated by examining post-welded properties. The effects of tempering temperature and time were separated through a series rapid isothermal tempering experiments. Hardness data from these experiments allowed the HAZ softening rate to be empirically quantified through fitting the JMAK equation. This material model was then validated by predicting HAZ softening in laser and resistance spot welds. Although the fitted JMAK constants could be used to predict post-weld HAZ hardness, they did not agree with the classic literature values associated with martensite tempering.
To understand why the JMAK coefficients did not match those of the classic martensite tempering literature, the softening data from one of the martensitic steels was re-examined. This study revealed that the softening process was a combination of two processes: carbide nucleation and carbide coarsening. The activation energies calculated for each process matched the classic literature values. Carbide coarsening dominated during tempering, which had a non-linear relation with change in hardness. The relationship between carbide coarsening and hardness was responsible for the softening kinetics measured from the rapid tempering experiments.